Chemistry Notes

Definitions

DALTON'S THEORY: all matter is made up of tiny indivisible particles which can neither be created nor destroyed

ENERGY LEVELS : fixed energy value that an electron in an atom may have

HEISENBERG UNCERTAINTY PRINCIPLE: it is impossible to measure at the same time both the velocity and position of an electron

AN ORBITAL: a region in space within which there is a high probability of finding an electron

THE PERIODIC LAW: when elements are arranged in order of increasing atomic number, the properties of the elements vary periodically

ATOMIC NUMBER: number of protons in the nucleus of that atom

MASS NUMBER: of an element is the sum of the number of protons and neutrons in the nucleus of an atom of that element

ISOTOPE: are atoms of the same element (i.e. same atomic number) that have different mass numbers due to the different number of neutrons in the nucleus

RELATIVE ATOMIC MASS: is the average of the mass numbers of the isotopes of the element, as they occur naturally, taking their abundances into account and compared with 1/12th of the mass of the carbon-12 isotope

THE AUFBAU PRINCIPLE: when building up the electronic configuration of an atom in its ground state, the electrons occupy the lowest available energy level

PAULI EXCLUSION PRINCIPLE: no more than two electrons can occupy an orbital and they must have opposite spin

HUND'S RULE: when two or more orbitals of equal energy are available, electrons occupy them singly before filling them n pairs

COMPOUND: is a substance that is made up of two or more different elements chemically combined

OCTET RULE: states when bonding occurs, atoms tend to reach an electron arrangement with eight electrons in outermost shell

IONIC BOND: force of attraction between oppositely charged ions in a compound

TRANSITION METAL: is one that forms at least one ion with a partially filled d sub-level

COVALENT BOND: formed when two atoms share a pair of electrons

VALENCY: the number of atoms of hydrogen or any other monovalent element with which each atom of that element combines

ELECTRONEGATIVITY: the relative attraction that an atom in a molecule has for the shared pair of electrons in a covalent bond

LAW OF CONSERVATION OF MASS: total mass of products of a chemical reaction is the same as total mass of reactants

LAW OF CONSERVATION OF MATTER: in any chemical reaction, matter is neither created nor destroyed, but merely changed from one form to another

ATOMIC RADIUS: half the distance between the nuclei of two atoms of the same element that are joined together by a single covalent bond

FIRST IONISATION ENERGY: of an element is the energy required to remove the most loosely bound electron from a neutral gaseous atom in its ground state

RADIOACTIVITY: is the spontaneous breaking up of unstable nuclei with the emission of one or more types of radiation

HALF-LIFE: time taken for half of the nucleus in any given sample to decay

RELATIVE MOLECULAR MASS: of a substance is the mass of one molecule of that substance compared with 1/12th of the mass of the carbon-12 isotope

ONE MOLE: is the amount of that substance which contains 6 x 1023 particles of that substance

BOYLE'S LAW: states that at constant temperature the volume of a fixed mass of gas is inversely proportional to its pressure

CHARLE'S LAW: states that at a constant pressure the volume of a fixed mass of gas is directly proportional to its temperature measured on the kelvin scale

GAY-LUSSAC'S LAW: states that in a reaction between gases the volume of the reacting gases and the volume of any gaseous products are in the ratio of small whole number provided that the volumes are measured at the same temperature and pressure

AVOGADRO'S LAW: states that equal volumes of gases contain equal number of molecules under the same conditions of temperature and pressure

IDEAL GAS: is one that obeys all the assumptions of the kinetic theory of gases under all conditions of temperature and pressure

EMPERICAL FORMULA OF A COMPOUND: formula which gives the simplest whole number ratio of the elements in the compound

MOLECULAR FORMULA OF A COMPOUND: formula that gives the actual number of each atom in the molecule